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Synthesis and properties of boron complexes of triphyrins(2.1.1).
|Title||Synthesis and properties of boron complexes of triphyrins(2.1.1).|
|Publication Type||Journal Article|
|Year of Publication||2013|
|Authors||Kuzuhara D, Xue Z, Mori S, Okujima T, Uno H, Aratani N, Yamada H|
|Journal||Chemical communications (Cambridge, England)|
|Date Published||2013 Oct 11|
Boron complexes of triphyrins(2.1.1) were prepared from free-base triphyrins(2.1.1) with phenylboron dichloride. The absorption spectrum of the meso-free β-alkyl-triphyrin boron complex in CH2Cl2 showed a broad weak band at around 640 nm assigned to transition from B-phenyl to the triphyrin, while that of the meso-aryl benzotriphyrin boron complex showed only Soret and Q bands.
|Alternate Journal||Chem. Commun. (Camb.)|