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Straightforward synthesis of alpha,beta-unsaturated thioesters via ruthenium-catalyzed olefin cross-metathesis with thioacrylate.
|Title||Straightforward synthesis of alpha,beta-unsaturated thioesters via ruthenium-catalyzed olefin cross-metathesis with thioacrylate.|
|Publication Type||Journal Article|
|Year of Publication||2008|
|Authors||van Zijl AW, Minnaard AJ, Feringa BL|
|Journal||The Journal of organic chemistry|
|Date Published||2008 Jul 18|
The cross-metathesis reaction of S-ethyl thioacrylate with a variety of olefins is effectively catalyzed by using a ruthenium benzylidene olefin metathesis catalyst. This reaction provides a convenient and versatile route to substituted alpha,beta-unsaturated thioesters, key building blocks in organic synthesis.
|Alternate Journal||J. Org. Chem.|