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Straightforward synthesis of alpha,beta-unsaturated thioesters via ruthenium-catalyzed olefin cross-metathesis with thioacrylate.
| Title | Straightforward synthesis of alpha,beta-unsaturated thioesters via ruthenium-catalyzed olefin cross-metathesis with thioacrylate. |
| Publication Type | Journal Article |
| Year of Publication | 2008 |
| Authors | van Zijl AW, Minnaard AJ, Feringa BL |
| Journal | The Journal of organic chemistry |
| Volume | 73 |
| Issue | 14 |
| Pagination | 5651-3 |
| Date Published | 2008 Jul 18 |
| Abstract | The cross-metathesis reaction of S-ethyl thioacrylate with a variety of olefins is effectively catalyzed by using a ruthenium benzylidene olefin metathesis catalyst. This reaction provides a convenient and versatile route to substituted alpha,beta-unsaturated thioesters, key building blocks in organic synthesis. |
| DOI | 10.1089/brain.2011.0005 |
| Alternate Journal | J. Org. Chem. |
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