Spectroscopic properties of chlorophyll f.

TitleSpectroscopic properties of chlorophyll f.
Publication TypeJournal Article
Year of Publication2013
AuthorsLi Y, Cai Z-L, Chen M
JournalThe journal of physical chemistry. B
Volume117
Issue38
Pagination11309-17
Date Published2013 Sep 26
Abstract

The absorption and fluorescence spectra of chlorophyll f (newly discovered in 2010) have been measured in acetone and methanol at different temperatures. The spectral analysis and assignment are compared with the spectra of chlorophyll a and d under the same experimental conditions. The spectroscopic properties of these chlorophylls have further been studied by the aid of density functional CAM-B3LYP and high-level symmetric adapted coupled-cluster configuration interaction calculations. The main Q and Soret bands and possible sidebands of chlorophylls have been determined. The photophysical properties of chlorophyll f are discussed.

DOI10.1371/journal.pone.0066791
Alternate JournalJ Phys Chem B