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Reductive amination of tertiary anilines and aldehydes.
|Title||Reductive amination of tertiary anilines and aldehydes.|
|Publication Type||Journal Article|
|Year of Publication||2013|
|Authors||Lv Y, Zheng Y, Li Y, Xiong T, Zhang J, Liu Q, Zhang Q|
|Journal||Chemical communications (Cambridge, England)|
|Date Published||2013 Oct 9|
An unprecedented oxidant-mediated reductive amination of tertiary anilines and aldehydes without external reducing agents was developed via the nucleophilic attack of the oxygen atom of the carbonyl group to in situ generated iminium ions, in which tertiary anilines were used as both nitrogen source and reducing agent for the first time.
|Alternate Journal||Chem. Commun. (Camb.)|