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A neutral Fe(III) compound exhibiting a two-step spin transition and dielectric anomalies.
|Title||A neutral Fe(III) compound exhibiting a two-step spin transition and dielectric anomalies.|
|Publication Type||Journal Article|
|Year of Publication||2013|
|Authors||Li Z-Y, Dai J-W, Gagnon KJ, Cai H-L, Yamamoto T, Einaga Y, Zhao H-H, Kanegawa S, Sato O, Dunbar KR, Xiong R-G|
|Journal||Dalton transactions (Cambridge, England : 2003)|
|Date Published||2013 Oct 1|
The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me)·H2O () was synthesized and characterized using powder/single-crystal X-ray diffraction, Mössbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound .
|Alternate Journal||Dalton Trans|