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Microelectrode Electrochemistry with Semiconducting Microelectrode Chips.
|Title||Microelectrode Electrochemistry with Semiconducting Microelectrode Chips.|
|Publication Type||Journal Article|
|Year of Publication||2013|
|Authors||Li T, Dong H, Fu X, He M, Li Y, Hu W|
|Journal||Small (Weinheim an der Bergstrasse, Germany)|
|Date Published||2013 Oct 7|
Well-defined semiconducting microelectrodes on silicon chips are prepared for new insights into microelectrode electrochemistry. Unique voltammetric features are observed due to a combined effect of enhanced mass transport from microelectrodes and rectifying nature of the semiconductor-electrolyte interface. The "diffusional independence" of single elements in certain arrays is also carefully studied.