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Highly active catalysts of bisphosphine oxides for asymmetric Heck reaction.
|Title||Highly active catalysts of bisphosphine oxides for asymmetric Heck reaction.|
|Publication Type||Journal Article|
|Year of Publication||2013|
|Authors||Hu J, Lu Y, Li Y, Zhou JS|
|Journal||Chemical communications (Cambridge, England)|
|Date Published||2013 Oct 21|
Bisphosphine oxides formed highly active asymmetric Heck catalysts, which were applied in asymmetric synthesis of pharmacologically active azacycles. Olefin insertion proceeded via cis pathways, different from P,N-ligands.
|Alternate Journal||Chem. Commun. (Camb.)|