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Facile synthesis of dibranched conjugated dienes via palladium-catalyzed oxidative coupling of N-tosylhydrazones.
|Title||Facile synthesis of dibranched conjugated dienes via palladium-catalyzed oxidative coupling of N-tosylhydrazones.|
|Publication Type||Journal Article|
|Year of Publication||2013|
|Authors||Jiang H, He L, Li X, Chen H, Wu W, Fu W|
|Journal||Chemical communications (Cambridge, England)|
|Date Published||2013 Oct 14|
A facile and highly regioselective Pd-catalyzed oxidative coupling of N-tosylhydrazones providing efficient access to 2,3-disubstituted-1,3-butadienes has been developed. This process features readily available starting materials and mild reaction conditions. Further transformations of the obtained dibranched 1,3-dienes, through Diels-Alder reactions and indene synthesis, are also demonstrated, which reveal their great potential for synthetic utility.
|Alternate Journal||Chem. Commun. (Camb.)|