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Dual role of allylsamarium bromide as a Grignard reagent and a single electron transfer reagent in the one-pot synthesis of terminal olefins.
|Title||Dual role of allylsamarium bromide as a Grignard reagent and a single electron transfer reagent in the one-pot synthesis of terminal olefins.|
|Publication Type||Journal Article|
|Year of Publication||2013|
|Authors||Li Y, Hu Y-Y, Zhang S-L|
|Journal||Chemical communications (Cambridge, England)|
|Date Published||2013 Nov 21|
The utility of allylsamarium bromide, both as a nucleophilic reagent and a single-electron transfer reagent, in the reaction of carbonyl compounds with allylsamarium bromide in the presence of diethyl phosphate is reported in this communication. From a synthetic point of view, a simple one-pot method for the preparation of terminal olefins is developed.
|Alternate Journal||Chem. Commun. (Camb.)|