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Catalytic enantioselective synthesis of vicinal dialkyl arrays.
| Title | Catalytic enantioselective synthesis of vicinal dialkyl arrays. |
| Publication Type | Journal Article |
| Year of Publication | 2008 |
| Authors | van Zijl AW, Szymanski W, López F, Minnaard AJ, Feringa BL |
| Journal | The Journal of organic chemistry |
| Volume | 73 |
| Issue | 18 |
| Pagination | 6994-7002 |
| Date Published | 2008 Sep 19 |
| Abstract | With a consecutive "asymmetric allylic alkylation (AAA)/cross-metathesis (CM)/conjugate addition (CA)" protocol it is possible to synthesize either stereoisomer of compounds containing a vicinal dialkyl array with excellent stereoselectivity. The versatility of this protocol in natural product synthesis is demonstrated in the preparation of the ant pheromones faranal and lasiol. |
| DOI | 10.1089/brain.2011.0005 |
| Alternate Journal | J. Org. Chem. |
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